What is the Difference Between Voltaic Cell and Electrolytic Cell?

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The main difference between a voltaic cell and an electrolytic cell lies in the type of reactions they are involved in and the energy source they use. Here are the key differences:

  • Voltaic Cell:
  • Also known as a galvanic cell, it uses the energy released during a spontaneous redox reaction to generate electricity.
  • Spontaneous redox reactions convert chemical energy to electric energy.
  • Electric energy is generated by redox reactions.
  • The cathode is the positive electrode, and the anode is the negative electrode.
  • Electrolytic Cell:
  • Consumes electrical energy from an external source to force a non-spontaneous redox reaction to occur.
  • Non-spontaneous redox reactions convert the electric energy to chemical energy.
  • Electric energy brings about a chemical reaction with the help of an external source.
  • Both types of cells have a cathode and anode side, with a consistent flow of electrons from the anode to the cathode.

In summary, a voltaic cell converts chemical energy into electrical energy using spontaneous redox reactions, while an electrolytic cell does the opposite, converting electrical energy into chemical energy to drive non-spontaneous redox reactions.

Comparative Table: Voltaic Cell vs Electrolytic Cell

Here is a table summarizing the differences between voltaic cells and electrolytic cells:

Feature Voltaic Cells (Galvanic Cells) Electrolytic Cells
Energy Flow Spontaneous redox reactions convert chemical energy to electric energy. Non-spontaneous redox reactions convert electrical energy to chemical energy with the help of an external source.
Direction Electric energy is generated by redox reactions. Electric energy brings about a chemical reaction with the help of an external source.
Applications Used in batteries. Used in purifying copper and electroplating.
Electrodes Anode is negative, cathode is positive. Anode is positive, cathode is negative.
Setup Half cells in separate containers connected through salt bridges. Electrodes in the same container in a molten or solution electrolyte.

Voltaic cells, also known as galvanic cells, use spontaneous redox reactions to generate electrical energy, while electrolytic cells use electrical energy from an external source to force a reaction.