What is the Difference Between Tartaric Acid and Citric Acid?

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The main difference between tartaric acid and citric acid lies in their natural sources and chemical properties. Here are the key differences between the two:

  • Source: Tartaric acid occurs naturally in grapes, while citric acid occurs naturally in citrus fruits.
  • Chemical Formula: Tartaric acid has the chemical formula C4H6O6, and citric acid has the chemical formula C6H8O7.
  • Protonation: Tartaric acid is diprotic, meaning it can release two hydrogen atoms to form a salt, while citric acid is triprotic, meaning it can release three hydrogen atoms to form a salt.
  • Taste: Tartaric acid is more astringent and sour than citric acid.
  • Uses: Both acids are used as natural food additives, giving a sour taste to the food, preventing bacterial growth, and acting as antioxidants. However, they are used in different applications. For example, tartaric acid is often used in baking powder and is essential in recipes with baking soda, while citric acid is used in a wider variety of foods and beverages.

Comparative Table: Tartaric Acid vs Citric Acid

Here is a table comparing the differences between tartaric acid and citric acid:

Feature Tartaric Acid Citric Acid
Source Grapes Citrus fruits
Tartness More astringent and sour Less astringent and more flavorful sourness
Acid Strength Stronger, about 2.7 times stronger than malic acid Comparatively weaker than tartaric acid
Ionization Two hydrogens can ionize Not mentioned
Wine Making Considered the principal wine acid, present in larger quantities Not the principal wine acid
Sour Gummies Provides an immediate punch of sour Provides a longer, smoother sour finish

Tartaric acid is found in grapes and is considered the principal wine acid, being stronger than citric acid and providing a more astringent and sour taste. Citric acid, on the other hand, comes from citrus fruits and is less astringent, offering a more flavorful sourness. In sour gummies, a combination of tartaric, citric, and malic acids is recommended to achieve the desired taste and texture.