What is the Difference Between Rydberg and Balmer Formula?

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The Rydberg and Balmer formulas are both used to predict the wavelength of light resulting from an electron moving between different energy levels in a hydrogen atom. However, there are some differences between the two formulas:

  1. Derivation: The Rydberg formula is a derivative of the Balmer formula.
  2. Terms: The Rydberg formula gives the wavelength in terms of the atomic number of the atom, while the Balmer formula gives the wavelength in terms of two integers, m and n.
  3. Application: Both formulas are used to represent the wavelength of a series of hydrogen spectrum lines, but the Rydberg formula is more general and can be applied to other elements and spectral lines.

Here is a summary of the differences between the Rydberg and Balmer formulas:

Feature Rydberg Formula Balmer Formula
Derivation Derived from Balmer formula Original formula
Terms Gives wavelength in terms of atomic number of the atom Gives wavelength in terms of two integers, m and n
Application More general, can be applied to other elements and spectral lines Specific to hydrogen spectrum lines

Both formulas are important in determining the wavelength of photons emitted from hydrogen atoms and are used in conjunction with the Bohr model.

Comparative Table: Rydberg vs Balmer Formula

The Rydberg and Balmer formulas are important formulas in chemistry that relate to the wavelengths of light emitted during atomic transitions. The key difference between the two formulas is that the Rydberg formula gives the wavelength in terms of the atomic number of the atom, while the Balmer formula gives the wavelength in terms of two integers, m and n. Here is a comparison between the two formulas:

Feature Rydberg Formula Balmer Formula
Purpose Describes the wavelengths of spectral lines in all hydrogen-like atoms. Describes the wavelengths of spectral lines in the visible region of the hydrogen atom.
Generalizability Works for all hydrogen-like atoms with a slight modification. Specific to the hydrogen atom and its visible spectral lines.
wavelength (λ) λ = RH / (n1^2 - n2^2). λ = RH / (n1^2 - n2^2), where n1 = 2, and n2 is any whole number between 3 and infinity.
Energy States n1 and n2 represent the initial and final energy states of the electron, respectively. n1 = 2 represents the initial energy state of the electron, and n2 represents the final energy state of the electron.

Both formulas are used to calculate the wavelengths of light emitted during atomic transitions, but the Balmer formula is a special case of the Rydberg formula that specifically deals with the visible spectral lines of the hydrogen atom.