What is the Difference Between Pyrolusite and Psilomelane?

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Pyrolusite and psilomelane are both oxide minerals containing manganese atoms, but they have some differences in their composition and structure. The key differences between pyrolusite and psilomelane are:

  1. Crystal System: Pyrolusite has a tetragonal crystal system, while psilomelane has a monoclinic crystal system.
  2. Luster: Pyrolusite has a metallic luster, whereas psilomelane has a sub-metallic luster.
  3. Streak Color: The streak color of pyrolusite is black to bluish-black, while the streak color of psilomelane is brownish-black.
  4. Composition: Pyrolusite consists essentially of manganese dioxide (MnO2) and is important as an ore of manganese. Psilomelane, on the other hand, is a group name for hard black manganese oxides, including hollandite and romanechite, and consists of hydrous manganese oxide with variable amounts of barium and potassium. Psilomelane often includes barium in its composition, while pyrolusite does not.

Both minerals are used as ores for manganese production, but pyrolusite is also used in the manufacture of spiegeleisen and ferromanganese, as well as in the production of various alloys.

Comparative Table: Pyrolusite vs Psilomelane

Pyrolusite and Psilomelane are both oxide minerals, but they have some differences in their properties. Here is a table comparing their key characteristics:

Property Pyrolusite Psilomelane
Crystal System Tetragonal Monoclinic
Luster Metallic Sub-metallic
Streak Color Black to Bluish-black Brownish-black
Chemical Formula MnO2 Mn2O3
Main Component Manganese Dioxide Manganese Oxide
Color Dark black to lighter gray, sometimes bluish Dark gray to black
Hardness 2 - 6½ 2 - 5
Specific Gravity 5.04 - 5.08 Not specified

Both minerals are used as ores for manganese production, but psilomelane more often includes barium in its composition than pyrolusite does.