What is the Difference Between O-Xylene and P-Xylene?

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The key difference between O-xylene and P-xylene is the position of the two methyl groups attached to the benzene ring. In O-xylene, the methyl groups are attached at adjacent substituent positions, while in P-xylene, the methyl groups are attached at opposite substituent positions.

Some additional differences between O-xylene and P-xylene include:

  • Melting Point: P-xylene has a higher melting point compared to O-xylene due to the methyl groups being separated in such a way that there is less strain in the P-xylene molecules, resulting in stronger attraction forces between them.
  • Production Processes: O-xylene is typically produced via cracking petroleum, while P-xylene is produced via catalytic reforming.
  • Applications: O-xylene is an important precursor to phthalic anhydride, which is used in the production of plasticizers. P-xylene is the principal precursor to terephthalic acid and dimethyl terephthalate, both of which are monomers used in the production of polyethylene terephthalate (PET) plastic bottles.

Both O-xylene and P-xylene are isomers of xylene, an organic compound with the chemical formula (CH3)2C6H4. Xylene is used as a solvent in various industries, including printing, rubber, and leather, and is also a component of ink, rubber, and adhesives.

Comparative Table: O-Xylene vs P-Xylene

The key difference between O-Xylene and P-Xylene is the position of the two methyl groups attached to the benzene ring. Here is a table comparing the two:

Property O-Xylene P-Xylene
Methyl Groups 1,2 positions (para positions) 1,4 positions (ortho positions)
Chemical Formula C₆H(CH₃)₂ C₆H(CH₃)₂
Boiling Point 138.5 °C (281.3 °F) 139 °C (282 °F)
Melting Point No available value Higher than O-Xylene
Density 0.87 g/mL (7.26 lb/U.S. gallon or 8.72 lb/imp gallon) 0.87 g/mL (7.26 lb/U.S. gallon or 8.72 lb/imp gallon)
Production Method Cracking petroleum Catalytic reforming

Both O-Xylene and P-Xylene are isomers of dimethylbenzene, and they are organic compounds with the chemical formula (CH₃)₂C₆H₄.