What is the Difference Between Molar Solution and Normal Solution?

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The main difference between a molar solution and a normal solution lies in the way they are defined and used in chemistry. Here are the key differences:

  1. Definition: A molar solution contains one mole of solute per liter of solution, and its concentration is expressed as the number of moles of solute dissolved per liter of solution (mol/L). A normal solution, on the other hand, is a solution containing one equivalent of solutes per liter of solution, and its concentration is expressed as the number of gram equivalents of solute per liter of solution.
  2. Stoichiometry: Molar solutions do not consider the stoichiometry of the solutes, while normal solutions do.
  3. Acid-Base Chemistry: In acid-base chemistry, normality is used to express the concentration of protons (H+) or hydroxide ions (OH−) in a solution, providing a more in-depth understanding of the solution's concentration. Molarity, however, is more commonly used in general chemistry applications.
  4. Neutralization Reactions: Normality is particularly useful for acid-base neutralization reactions, where identical volumes of any acid solution will exactly neutralize identical volumes of a base solution, regardless of their molarity.

In summary, molar solutions are defined by the number of moles of solute per liter of solution, while normal solutions are defined by the number of equivalents of solute per liter of solution. Molarity is more commonly used in general chemistry, while normality is more relevant in acid-base chemistry.

Comparative Table: Molar Solution vs Normal Solution

The main difference between a molar solution and a normal solution lies in the way they are defined and prepared. Here is a comparison table highlighting the differences between the two:

Parameter Molar Solution Normal Solution
Definition A molar solution contains one mole of solute per liter of solution. A normal solution contains 1 gram equivalent weight of solute per liter of solution.
Unit of Concentration Molarity (mol/L). Normality (N).
Preparation To prepare a molar solution, dissolve the gram molecular weight of the solute in 1 liter of solution. To prepare a normal solution, dissolve 1 gram equivalent weight of solute in 1 liter of solution.
Stoichiometry Molar solutions do not consider the stoichiometry of the solutes. Normal solutions consider the stoichiometry as well.

In summary, a molar solution is defined by the number of moles of solute dissolved per liter of solution, while a normal solution is defined by the gram equivalent weight of solute per liter of solution. Molar solutions ignore the stoichiometry of the solutes, whereas normal solutions take it into account.