What is the Difference Between Metal Carbonate and Metal Hydrogen Carbonate?

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The key difference between metal carbonate and metal hydrogen carbonate lies in the anions they contain:

  • Metal Carbonate: These inorganic compounds contain a metal cation and a carbonate anion, which has a -2 electrical charge. Examples of metal carbonates include calcium carbonate (CaCO3) and sodium carbonate (Na2CO3).
  • Metal Hydrogen Carbonate: Also known as metal bicarbonates, these inorganic compounds contain a metal cation and a bicarbonate anion, which has a -1 electrical charge. Examples of metal hydrogen carbonates include sodium bicarbonate (NaHCO3) and potassium bicarbonate (KHCO3).

Both metal carbonates and metal hydrogen carbonates are basic in nature and react with acids to produce a salt, water, and carbon dioxide. For example:

  • Acid + Metal Carbonate → Salt + Water + Carbon Dioxide
  • Acid + Metal Hydrogen Carbonate → Salt + Water + Carbon Dioxide

In summary, the main difference between metal carbonate and metal hydrogen carbonate is the type of anion they contain (carbonate or bicarbonate) and their respective electrical charges. Both compounds are basic and react with acids to produce similar products.

Comparative Table: Metal Carbonate vs Metal Hydrogen Carbonate

Here is a table comparing the differences between metal carbonate and metal hydrogen carbonate:

Property Metal Carbonate Metal Hydrogen Carbonate
Chemical Formula Generally represented as MCO3 Generally represented as MHCO3
Ions Involved Contains a metal cation and a carbonate anion (CO32-) Contains a metal cation, a hydrogen ion, and a bicarbonate anion (HCO3-)
Acidity Less acidic compared to metal hydrogen carbonates More acidic compared to metal carbonates
Reaction with Acids Reacts with acids to produce carbon dioxide, salt, and water Reacts with acids to produce carbon dioxide, salt, and water
Heat Decomposition Generally decomposes on heating to produce carbon dioxide and a metal oxide Decomposes on heating to produce carbon dioxide and a metal oxide

In summary, the main difference between metal carbonate and metal hydrogen carbonate is the presence of a hydrogen ion in the latter. Both compounds react with acids to produce carbon dioxide, salt, and water, and they decompose on heating to produce carbon dioxide and a metal oxide. Metal hydrogen carbonates are more acidic compared to metal carbonates.