What is the Difference Between Ionic Bonding and Metallic Bonding?

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The main difference between ionic and metallic bonding lies in the way atoms are bonded together and the properties that result from these bondings. Here are the key differences between ionic and metallic bonding:

  1. Formation of bonds: Ionic bonding occurs when two oppositely charged ions are formed by the transfer of one or more electrons from a metal atom to a non-metal atom. Metallic bonding, on the other hand, is created when metal atoms lose their outermost electrons to form positively charged ions, resulting in a sea of delocalized electrons.
  2. Charges: Ionic bonds involve the formation of positive and negative ions, whereas metallic bonds involve the creation of positively charged ions and a delocalized sea of electrons.
  3. Properties of materials: Ionic compounds are typically hard and brittle due to the strong electrostatic forces holding the ions together. Metals, which exhibit metallic bonding, have high electrical and thermal conductivity, malleability, ductility, and a characteristic metallic luster.
  4. Melting and boiling points: Ionic bonds generally have higher melting and boiling points than metallic bonds due to the strong attractions between the oppositely charged ions.
  5. Strength of bonds: Covalent bonds are generally stronger than ionic bonds, except for certain cases like carbon, silicon, and diamond. Metallic bonds are extremely strong due to the crystalline structure and the delocalized nature of the valence electrons.

In summary, ionic bonding involves the transfer of electrons, resulting in positively and negatively charged ions, while metallic bonding involves the delocalization of electrons in a sea of positive ions. These differences in bonding lead to distinct properties of materials, such as hardness, brittleness, electrical conductivity, and malleability.

Comparative Table: Ionic Bonding vs Metallic Bonding

Here is a table comparing ionic bonding and metallic bonding:

Property Ionic Bonding Metallic Bonding
Definition The electrostatic force of attraction between two oppositely charged ions formed when one atom donates valence electrons to another atom. The chemical bond formed between a cloud of free electrons and the positively charged ions in a lattice structure.
Occurrence Joins metals to non-metals. Joins metals to metals.
State of Matter Solid-state. Solid-state at room temperature but can be liquified by increasing temperature.
Malleability Non-malleable. Malleable.
Ductility Non-ductile. Ductile.
Melting Point Higher melting point. High melting point.
Boiling Point Lower boiling point. High boiling point.
Conductivity Good electrical conductivity in molten and aqueous states. High thermal and electrical conductivities.
Electronegativity Influence The strength of ionic bonding is greatly influenced by the electronegativity difference between the positive and negative ions. Electronegativity has no influence on metallic bonding since the same type of atoms are involved.
Strength of Bonding Ionic bonding is much stronger than metallic bonding. Metallic bonding is weaker than ionic bonding.

To summarize, ionic bonding occurs between oppositely charged ions, joining metals to non-metals, while metallic bonding is the electrostatic attraction between a sea of free electrons and positively charged ions in a lattice structure, joining metals to metals. Metallic bonding is generally weaker than ionic bonding and has higher melting and boiling points, malleability, and ductility compared to ionic bonding.