What is the Difference Between Iodide and Triiodide?

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The main difference between iodide and triiodide lies in the number of iodine atoms and their charges:

  • Iodide: Iodide (I⁻) is a simple monatomic anion, consisting of a single iodine atom with a -1 charge. It is one of the anions of iodine and is often found in aqueous solutions.
  • Triiodide: Triiodide (I⁻³) is a polyatomic anion composed of three iodine atoms, also with a -1 overall charge. It is formed by combining aqueous solutions of iodide salts and iodine.

Both iodide and triiodide are anions of iodine and carry a negative charge. They are often found together in aqueous solutions, existing in equilibrium with the diiodide anion. In low concentrations, triiodide solutions appear yellow, but they turn red-brown at high concentrations.

Comparative Table: Iodide vs Triiodide

The key difference between iodide and triiodide is that iodide is a single iodine atom with a -1 charge, whereas triiodide is a combination of three iodine atoms with a -1 overall charge. Here is a table summarizing the differences between iodide and triiodide:

Property Iodide Triiodide
Iodine atoms 1 3
Charge -1 -1 (overall)
Color Iodide solutions are typically colorless or pale yellow Triiodide solutions can be red-brown at high concentrations and yellow at lower concentrations
Relation Iodide is a single iodine atom anion Triiodide is a combination of three iodine atoms with a single anion
Solutions Iodide and triiodide usually exist together in aqueous solutions, having an equilibrium with the diiodide anion

Both iodide and triiodide are anions of iodine and are negatively charged. They are commonly found in solutions like Lugol's iodine solution and tincture of iodine solution.