What is the Difference Between Galvanic Cell and Concentration Cell?

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The main difference between a galvanic cell and a concentration cell lies in the composition of the half-cells and their purpose:

  • Galvanic Cell: A galvanic cell is a type of electrochemical cell that uses spontaneous redox reactions to generate electrical energy. It typically consists of two half-cells with different electrodes and electrolytes, and it can produce electrical energy as long as there is a driving force in the form of a spontaneous redox reaction.
  • Concentration Cell: A concentration cell is a specific type of galvanic cell made of two half-cells with the same electrodes but different concentrations of the same electrolyte. The purpose of a concentration cell is to dilute the more concentrated solution and concentrate the more dilute solution, creating a voltage as the cell reaches an equilibrium by transferring electrons from the cell with the lower concentration to the cell with the higher concentration.

In summary:

Feature Galvanic Cell Concentration Cell
Type Generates electrical energy through spontaneous redox reactions Establishes equilibrium between two half-cells with the same electrodes but different concentrations
Composition Different electrodes and electrolytes in each half-cell Same electrodes and electrolyte, but different concentrations in each half-cell
Purpose Produces electrical energy Dilutes the more concentrated solution and concentrates the more dilute solution

Comparative Table: Galvanic Cell vs Concentration Cell

Here is a table summarizing the differences between galvanic cells and concentration cells:

Feature Galvanic Cell Concentration Cell
Definition A type of electrochemical cell that generates electrical energy through spontaneous redox reactions. A specific type of galvanic cell where the two half-cells have the same electrodes but different concentrations.
Electrodes Can be made of the same or different substances. Must be made of the same substance.
Electrolytes Can have the same or different electrolytes in the two half-cells. Has identical electrodes in both half-cells.
Concentration Does not have the same concentration of solution on both sides. Has the same concentration of solution on both sides, but with differing concentrations of the reacting species.
Cell Potential Produces a voltage that can be measured using a voltmeter. The cell potential is dependent on concentration and can be calculated using the Nernst Equation.

Galvanic cells involve spontaneous redox reactions to generate electrical energy, while concentration cells focus on establishing equilibrium by transferring electrons between two half-cells with the same electrodes but different concentrations. The key difference between the two is the similarity of the half-cells and their concentrations. Concentration cells are a specific type of galvanic cell with the same electrodes but different concentrations, while galvanic cells can have different electrodes and electrolytes in their half-cells.