What is the Difference Between Equilibrium Constant and Reaction Quotient?

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The main differences between the equilibrium constant (K) and the reaction quotient (Q) are:

  1. Time: K represents the concentrations at equilibrium, while Q can use the concentrations at any given time during the reaction.
  2. Value: The value of Q changes during a reaction, whereas the value of K does not change unless the temperature changes.
  3. Equilibrium: Q can be calculated at any point during the reaction, whether it is at equilibrium or not. In contrast, K is calculated only when the reaction reaches equilibrium.
  4. Comparison: By comparing Q and K, we can determine in which direction the reaction will proceed initially.

In summary, the equilibrium constant (K) is a measure of the reaction's state at equilibrium, while the reaction quotient (Q) describes the state of the system with respect to equilibrium at any given time during the reaction. Comparing Q and K allows us to understand the direction in which the reaction will proceed.

Comparative Table: Equilibrium Constant vs Reaction Quotient

The equilibrium constant (K) and the reaction quotient (Q) are both used to describe the state of a chemical reaction with respect to equilibrium. However, they differ in several aspects:

Equilibrium Constant (K) Reaction Quotient (Q)
Represents the ratio of products to reactants at equilibrium Represents the ratio of products to reactants at any point during the reaction
Unitless Units may vary depending on the reaction
Value does not change unless the temperature changes Value changes during the reaction
Helps determine the direction in which a reaction will shift to achieve equilibrium Can be compared to K to determine if a reaction is at equilibrium or if it will shift to the right or left to reach equilibrium

In summary, the equilibrium constant (K) is a constant value that represents the ratio of products to reactants at equilibrium, while the reaction quotient (Q) is a variable value that represents the ratio of products to reactants at any point during the reaction. Comparing Q and K can help determine the direction in which a reaction will proceed to reach equilibrium.