What is the Difference Between Degenerate and Non-degenerate Semiconductor?

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Degenerate and non-degenerate semiconductors differ in terms of doping levels and their electronic properties. Here are the key differences between the two:

  1. Doping Levels: A degenerate semiconductor has a high level of doping, causing the material to act more like a metal than a semiconductor. On the other hand, a non-degenerate semiconductor has moderate levels of doping, with dopant atoms well separated from each other and exhibiting negligible interactions.
  2. Electronic Properties: In a degenerate semiconductor, the injection of electrons or holes is only possible from the Fermi energy level. In contrast, non-degenerate semiconductors can form two types of contacts with organic materials.
  3. Energy Band Structure: Degenerate semiconductors have very little space between the valence band edge and the conduction band edge, while non-degenerate semiconductors have a larger gap between the valence band and the conduction band.
  4. Temperature Dependence: Degenerate semiconductors do not obey the law of mass action, which relates intrinsic carrier concentration with temperature and bandgap. In contrast, non-degenerate semiconductors follow this law, and their increase in conductivity with temperature is a typical trait.

In summary, degenerate semiconductors are heavily doped materials that exhibit properties intermediate between semiconductors and metals, while non-degenerate semiconductors have moderate doping levels and maintain the properties of traditional semiconductors. Non-degenerate semiconductors are used in various applications, such as solar cells, light-emitting diodes, and many other electronic devices.

Comparative Table: Degenerate vs Non-degenerate Semiconductor

Here is a table comparing the differences between degenerate and non-degenerate semiconductors:

Feature Degenerate Semiconductors Non-degenerate Semiconductors
Definition A semiconductor with a high level of doping, causing their functions to be similar to that of metals. A semiconductor containing moderate levels of doping, exhibiting separate energy levels for dopant atoms with negligible interactions.
Doping Level High level of doping, typically 10^16 atoms/cm^3 or higher. Lower level of doping compared to degenerate semiconductors.
Fermi Energy Fermi energy level is close to the band edge, resulting in very little space between the valence and conduction bands. Fermi energy level is at least 3kT away from either band edge, creating a larger gap between the valence and conduction bands.
Conductivity Increases with temperature due to the high level of doping. Exhibits moderate conductivity.
Examples Silicon, germanium, and silicon-germanium alloys. Moderately doped silicon, germanium, and other semiconductor materials.

In summary, degenerate semiconductors have a high level of doping, causing their functions to be similar to that of metals, while non-degenerate semiconductors have moderate levels of doping and exhibit separate energy levels for dopant atoms with negligible interactions.