What is the Difference Between Benzene and Phenyl?

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Benzene and phenyl are related but distinct chemical compounds. The key difference between them lies in their structure and composition:

  • Benzene is a cyclic hydrocarbon containing six carbon atoms and six hydrogen atoms, with alternating double and single bonds between the carbon atoms. Its molecular formula is C6H6.
  • Phenyl is a derivative of benzene, created by removing one hydrogen atom from the benzene ring. This leaves the phenyl group with five hydrogen atoms and a molecular formula of C6H5.

In essence, a phenyl group is a benzene ring with one hydrogen atom replaced by a bond to another molecule or chain. Phenyl groups are often used as substituents in other organic compounds, while benzene itself is a parent compound for many important aromatic hydrocarbons. While both benzene and phenyl groups have aromatic character, phenyl alone is not as stable as benzene.

Comparative Table: Benzene vs Phenyl

Here is a table comparing the differences between benzene and phenyl:

Property Benzene Phenyl
Chemical Formula C6H6 C6H5
Hydrogen Atoms 6 5
Aromaticity Yes Yes
Electron-withdrawing Substituent No Yes
Stability Stable Less stable than benzene
Hydrophobicity Non-polar Non-polar
Oxidation and Reduction Resistance More reactive Less reactive

The key difference between benzene and phenyl is that benzene is a cyclic hydrocarbon containing only carbon and hydrogen atoms, while phenyl is a derivative of benzene, created by the removal of a hydrogen atom. Benzene has six hydrogen atoms, whereas phenyl has five hydrogen atoms. Phenyl groups are hydrophobic and non-polar, and they do not easily undergo oxidations or reductions due to their aromaticity.