What is the Difference Between Alkali and Alkaline?

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The terms "alkali" and "alkaline" are often used to describe substances with a high pH level (greater than 7), making them basic rather than acidic. However, there are some differences between the two terms:

  1. Alkali:
  • Refers to a base dissolved in a solvent, usually water.
  • Acts as a noun, indicating a specific substance.
  • Examples include sodium hydroxide (NaOH) and potassium hydroxide (KOH).
  1. Alkaline:
  • Refers to the adjective form of a substance with a high pH level.
  • Can be used interchangeably with the term "base".

In a non-scientific context, the terms "alkali" and "alkaline" can be used to describe the same thing, as they both refer to substances with a high pH level. However, when discussing the terms in a chemical context, there is a difference:

  • Alkali:
  • Refers to any of the elements in the first group of the Periodic Table, such as lithium (Li), sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), and francium (Fr).
  • These elements have one free electron in their outermost shell, making them highly reactive.
  • Alkaline Earth Metals:
  • Refers to any of the elements in the second group of the Periodic Table, such as beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).
  • These elements have two electrons in their outermost shell, making them less reactive than alkali metals.

In summary:

  • Alkali: A base dissolved in a solvent, usually water, and refers specifically to the elements in the first group of the Periodic Table.
  • Alkaline: An adjective used to describe substances with a high pH level or a base.

Comparative Table: Alkali vs Alkaline

The difference between alkali and alkaline lies in the elements they represent and their properties. Here is a table comparing the two:

Property Alkali Alkaline
Definition Alkali refers to the elements in Group 1 of the periodic table, which are highly reactive and have one valence electron. Alkaline refers to the elements in Group 2 of the periodic table, which are less reactive than alkali metals and have two valence electrons.
Examples Lithium (Li), Sodium (Na), Potassium (K), Rubidium (Rb), Cesium (Cs), and Francium (Fr). Beryllium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba), and Radium (Ra).
Reactivity Alkali metals are more reactive than alkaline earth metals. Alkaline earth metals are less reactive than alkali metals.
Softness Alkali metals are softer than alkaline earth metals. Alkaline earth metals are harder than alkali metals.
Melting Point Alkali metals have lower melting points than alkaline earth metals. Alkaline earth metals have higher melting points than alkali metals.
Cations Alkali metals form +1 cations. Alkaline earth metals form +2 cations.

In summary, alkali metals are highly reactive and have one valence electron, while alkaline earth metals are less reactive and have two valence electrons. Alkali metals are softer and have lower melting points than alkaline earth metals, and they form +1 cations, while alkaline earth metals form +2 cations.