What is the Difference Between Aerogel and Xerogel?

🆚 Go to Comparative Table 🆚

The main difference between aerogel and xerogel lies in the drying process and the resulting properties of the materials:

  • Aerogel: Aerogels are formed when the liquid from the gel is extracted at a supercritical state, which means the liquid is under high pressure and temperature, approaching a critical point. Aerogels have a low density and a larger surface area compared to xerogels. They are typically monolithic, with little to no shrinkage or cracking. Aerogels are often used in insulation, aerospace, and energy applications due to their low density, high porosity, and excellent thermal insulation properties.
  • Xerogel: Xerogels are formed when the liquid from the gel evaporates at room temperature, or sometimes with the help of an oven dryer. Unlike aerogels, xerogels can have shrinkage and cracking due to the slow drying process. Xerogels have a higher density compared to aerogels. They are used in various applications such as drug delivery, catalysis, and sorbents.

In summary, aerogels are produced through a supercritical drying process, resulting in low-density, highly porous materials with minimal shrinkage or cracking. On the other hand, xerogels are produced by evaporating the liquid at room temperature or using an oven dryer, resulting in higher density materials with possible shrinkage and cracking.

Comparative Table: Aerogel vs Xerogel

The main differences between aerogels and xerogels arise from their preparation methods, porosity, density, and shrinkage. Here is a table summarizing their key differences:

Property Aerogel Xerogel
Formation Process Liquid from the gel is extracted at a supercritical state Liquid from the gel is evaporated at room temperature
Porosity Generally has a lower porosity (15-50%) Generally has a higher porosity
Density Lower density compared to xerogels Higher density compared to aerogels
Shrinkage Little to no shrinkage during the drying process High shrinkage during the drying process with unhindered shrinkage
Surface Area Smaller surface area compared to aerogels Larger surface area compared to xerogels

Aerogels and xerogels are both solid gel materials, but they differ in their structure and properties due to the differences in their formation processes. Aerogels form when the liquid from the gel is extracted at a supercritical state, while xerogels form when the liquid from the gel is evaporated at room temperature. These differences in the preparation methods result in distinct characteristics, such as porosity, density, and shrinkage, which determine their applications.