What is the Difference Between Acetylene and Ethylene?

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The main difference between acetylene and ethylene lies in their chemical structure and bonding. Here are the key differences:

  • Chemical Formula: Acetylene has the chemical formula C2H2, while ethylene has the chemical formula C2H4.
  • Bonding: Acetylene has a triple bond between the two carbon atoms, resulting in a linear geometry for the molecule. Ethylene has a double bond between the carbon atoms and a bond angle of about 120 degrees.
  • Hybridization: In acetylene, both carbons are sp-hybridized, resulting in two sp hybrid orbitals oriented along the x-axis and two unhybridized p orbitals oriented perpendicularly along the y and z axes. In ethylene, both carbon atoms are sp2-hybridized, resulting in three sp2 hybrid orbitals oriented in a trigonal planar geometry.

Similarities between acetylene and ethylene include:

  • Both are small hydrocarbons composed only of carbon atoms and hydrogen atoms.
  • Both are colorless gases.
  • Both are flammable gases.
  • Both have planar structures.

Comparative Table: Acetylene vs Ethylene

The main difference between acetylene and ethylene is the type of bond between the carbon atoms in their chemical structure. Here is a table comparing their differences:

Feature Acetylene (C2H2) Ethylene (C2H4)
Bond Type Triple bond Double bond
Molecular Geometry Linear Planar
Bond Angles 180° 120°
Hybridization sp sp², sp
Hindered Rotation Yes No
Stability Unstable Stable
Uses Welding, cutting, synthetic material production

Both acetylene and ethylene are small hydrocarbons composed only of carbon atoms and hydrogen atoms, and they are colorless and flammable gases. However, acetylene has a triple bond between its two carbon atoms, while ethylene has a double bond. Acetylene's molecular geometry is linear due to the triple bond, whereas ethylene is a planar molecule.